This is a pretty easy modification, and only requires one small change.
First, open up the Main Index Template for editing (index.php) through the WordPress administration "Theme Editor".
Search for the following line:
<?php $my_query = new WP_Query('category_name=products&showposts=12'); while ($my_query->have_posts()) : $my_query->the_post(); // check for product large image
Locate in the line where it says "showposts=12". Change the number "12" to whatever number you like.
NOTE: It's usually best to keep the number a multiple of 3, since the design layout is optimized to fit 3 thumbnail images across. (ie. 3, 6, 9, 12, 15, 18, etc.)
Save the file.
That's it.